Anatase-driven charge transfer involving a spin transition in cobalt iron cyanide nanostructures.
نویسندگان
چکیده
A charge transfer between Fe and Co in cobalt hexacyanoferrate has been observed for the first time by anatase doping. The charge transfer, which involves a spin transition at the Co site, is supported by high-resolution XANES spectra. EXAFS evidenced a consistent change (10%) of the Co-N first shell.
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ورودعنوان ژورنال:
- Physical chemistry chemical physics : PCCP
دوره 17 35 شماره
صفحات -
تاریخ انتشار 2015